In Situ Characterization of the Initial Effect of Water on Molecular Interactions at the Interface of Organic/Inorganic Hybrid Systems
نویسندگان
چکیده
Probing initial interactions at the interface of hybrid systems under humid conditions has the potential to reveal the local chemical environment at solid/solid interfaces under real-world, technologically relevant conditions. Here, we show that ambient pressure X-ray photoelectron spectroscopy (APXPS) with a conventional X-ray source can be used to study the effects of water exposure on the interaction of a nanometer-thin polyacrylic acid (PAA) layer with a native aluminum oxide surface. The formation of a carboxylate ionic bond at the interface is characterized both with APXPS and in situ attenuated total reflectance Fourier transform infrared spectroscopy in the Kretschmann geometry (ATR-FTIR Kretschmann). When water is dosed in the APXPS chamber up to 5 Torr (~28% relative humidity), an increase in the amount of ionic bonds at the interface is observed. To confirm our APXPS interpretation, complementary ATR-FTIR Kretschmann experiments on a similar model system, which is exposed to an aqueous electrolyte, are conducted. These spectra demonstrate that water leads to an increased wet adhesion through increased ionic bond formation.
منابع مشابه
Interaction of Prolin, Leucine and methylurea with inorganic cluster [(PO4)M12O36].nH2O; (M = Mo, W)
Three new inorganic-organic hybrid materials based on heteropolyoxometalates, [L-C6H14NO2]3[(PO4)Mo12O36].3H2O (1), [L-C5H10NO2]3[(PO4)W12O36].H2O (2), and [C2H7N2O]3[(PO4)W12O36]. 4H2O (3), where C6H14NO2, C5H10NO2, and C2H7N2O are protonated L-leucine, L-proline, and methylurea, respectively, have been synthesized and structurally characterized by some physico-chemical methods. Elemental anal...
متن کاملEffect of TiO2 Nanofiber Density on Organic-Inorganic Based Hybrid Solar Cells (RESEARCH NOTE)
Abstract In this work, a comparative study of hybrid solar cells based on P3HT and TiO2 nanofibers was accomplished. Electrospinning, a low cost production method for large area nanofibrous films, was employed to fabricate the organic-inorganic hybrid solar cells based on poly (3-hexylthiophene) and TiO2 nanofibers. The performance of the hybrid solar cells was analyzed for four density levels ...
متن کاملDesigning a hybrid quantum controller for strongly eigenstate controllable systems
In this paper, a new quantum hybrid controller for controlling the strongly eigenstate controllable systems, is designed. For this purpose, a Lyapunov control law is implemented when the target state is in reachable set of the initial state. On the other hand, if the target state is not in the reachable set of the given initial state, based on Grover algorithm, a new interface state that the t...
متن کاملConductive Polythiophene Nanoparticles Deposition on Transparent PET Substrates: Effect of Modification with Hybrid Organic-inorganic Coating (RESEARCH NOTE)
In this work, Poly(ethyleneterephthalate) (PET) substrate was treated using KOH solution and was modified using hybrid O-I coating containing PCL )polycaprolactone( as organic phase and TEOS )tetraethoxysilane( as inorganic phase. The coating was prepared through a sol-gel process and applied on the surface by dip coater. Then, electrically conducting polythiophene (PTh) nanoparticles were depo...
متن کاملA Brief Review of Nanoindentation Technique and its Applications in Hybrid Nanocomposite Coatings
Nanoindentation techniques are widely used for the study of nanomechanical properties of thin nanocomposite coatings. Theoretical concepts and practical use of nanoindentation method are summarized with reporting the applications of these tests in characterization of some particular thin nanocomposite hybrid coatings prepared by sol-gel process. The better mechanical properties can be obtained ...
متن کامل